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Pyridine-3-carboxylic acid (nicH) reacts with iron(II) chloride tetra­hydrate in a methanol–water mixture to form the title compound, [Fe(C6H4NO2)2(H2O)4]. The FeII atom is in a slightly distorted octa­hedral coordination. The crystal structure is stabilized by O—H...O hydrogen bonds involving all the water H atoms and the carboxyl­ate groups.
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