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The asymmetric unit of the title compound, [Ru(C2H3N)(phen)(terpy)](PF6)2 [phen is 1,10-phenanthroline (C12H8N2) and terpy is 2,2':6',2''-terpyridine (C15H11N3)] contains a monomeric [Ru(CH3CN)(phen)(terpy)]2+ cation and two hexafluoro­phosphate anions. The ligand environment about the Ru atom is distorted octahedral. The Ru-N distances are in the range 1.933 (5)-2.083 (5) Å and the Ru-N(aceto­nitrile) distance is 2.016 (7) Å.

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The title compound, [RuCl(C24H16N2)(C15H11N3)]PF6, consists of a monomeric RuII complex cation and a hexa­fluoro­phosphate anion. The coordination environment about the RuII atom is distorted octa­hedral, where the 2,2':6',2''-terpyridine (terpy) ligand is coordinated in a meridional fashion, the 4,7-diphen­yl-1,10-phenanthroline (dpphen) ligand is coordinated in a cis fashion and the Cl atom is trans to one of the dpphen N atoms. The Ru-N bond distances are in the range 1.956 (5)-2.096 (5) Å and the Ru-Cl distance is 2.403 (2) Å.
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