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The structure of the title compound, [V(C5H5)2Cl(C2H3N)][FeCl4], a potential spermicidally active species, has been determined. This compound has a typical bent metallocene structure, in which two η5-bonded cyclo­penta­dienyl rings, an N-coordinated acetonitrile molecule and a Cl ligand occupy tetrahedral positions around the VIV atom. The V—N bond length was found to be 2.087 (2) Å.
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