(S)-(Acetyl­acetonato-κ²O,O′)[2-(1-aminoethyl)­phenyl-κ²C¹,N]­palladium(II)

The title complex, [Pd(C₈H₁₀N)(C₅H₇O₂)], has been prepared to be used as a building block for a co-crystallization experiment.

(S)-[2-(1-Amino­ethyl)­phenyl-κ²C¹,N](hexa­fluoro­acetyl­acetonato-κ²O,O′)palladium(II)

The title complex, [Pd(C₈H₈N)(C₅HF₆O₂)], has been prepared to be used as a building block for a co-crystallization experiment.

rac-[2-(1-Amino­ethyl)phenyl-κ²C¹,N](hexafluoro­acetyl­acetonato-κ²O,O′)palladium(II)

From a quasi-racemic mixture of structurally related pallad­ium complexes of opposite chirality, no quasi-racemic crystals were obtained. Rather, ligand exchange resulted in conventional racemic crystals. The crystal and molecular structures of the title complex, [Pd(C₈H₁₁N)(C₅F₆O₂)], are reported.

Tri­carbonyl­{η⁶-(S,S)-1-[2-methoxy-3,6-bis­(trimethyl­silyl)­phenyl]-N,N-di­methyl­ethyl­amine}­chromium(0)

The title complex, [Cr(C₁₇H₃₃NOSi₂)(CO)₃], has the typical three-legged piano-stool structure expected for η⁶-arenetri­carbonyl­chromium compounds. The conformation is staggered with respect to the methoxy group of the arene ring and one of the carbonyl ligands.

Tri­carbonyl­[η⁶-(R)-N,N-di­methyl-1-phenyl­ethyl­amine]­chromium(0)

The title complex, [Cr(C₁₀H₁₅N)(CO)₃], has a typical three-legged piano-stool structure, as is expected for an η⁶-arene–tri­carbonyl­chromium compound. The conformation is staggered with respect to the side chain and one of the carbonyl ligands. The side chain bearing the stereogenic centre adopts a conformation with the H atom pointing downwards, leaving the di­methyl­amine group above the ring plane.