research papers
A metal coordination polymer has been synthesized by the reaction of Mn(ClO4)2·6H2O with 3,6-bis(pyridin-2-yl)-1,2,4,5-tetrazine (bptz) and (Bu3N)3[Mo(CN)8] at room temperature. X-ray diffraction analysis reveals that the compound is a new three-dimensional coordination polymer with a PtS-type network. Magnetic investigation shows antiferromagnetic coupling between adjacent Mn2+ cations.
research papers
A ZnII coordination polymer has been prepared by reaction of ZnCl2·4H2O with 1,4-phenylenediacetic acid and 1,3-bis[(1H-1,2,4-triazol-1-yl)methyl]benzene in H2O. Single-crystal X-ray diffraction analysis reveals that the compound possesses a novel one-dimensional rotaxane-like structure.