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The first isolable homoleptic pyrene transition metal complexes are presented. In each case, the pyrene ligands are parallel and sandwich the transition metals in one of two possible inversion-related sites.

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The first structures of homoleptic 2,2'-bi­pyridine metalates(-I) of iron and cobalt are shown to have reduced bi­pyridine ligands. One structure is cocrystallized with an anthracene radical anion, while the other is cocrystallized with neutral anthracene.
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