Bis(pyrene)metal complexes of vanadium, niobium and titanium: isolable homoleptic pyrene complexes of transition metals

B. E. Kucera, R. E. Jilek, W. W. Brennessel and J. E. Ellis

The first isolable homoleptic pyrene transition metal complexes are presented. In each case, the pyrene ligands are parallel and sandwich the transition metals in one of two possible inversion-related sites.

Keywords: crystal structure; pyrene; polycyclic aromatic hydrocarbons; homoleptic complexes; sandwich compounds; paramagnetic compounds; vanadium; niobium; titanium.

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