The coordination polymer poly[[aqua([mu]-oxalato)[1H-1,2,4-triazole-5(4H)-thione]cadmium(II)] monohydrate]

The title complex is a two-dimensional metal-organic framework, with the Cd^II cation coordinated by three oxalate ligands, a 1H-1,2,4-triazole-5(4H)-thione ligand and a water mol­ecule. The CdO₆S and oxalate units form an extended two-dimensional layered structure.

[2,5-Bis(2,2′-bipyridyl-6-yl)-3,4-di­aza­hexa-2,4-diene]di­chlorido­mangan­ese(II): from a mononuclear compound to a three-dimensional supra­molecular framework through C—H...Cl hydrogen bonds and π–π stacking inter­actions

A supra­molecular architecture based on C—H...Cl and π–π stacking inter­actions was obtained for a mononuclear Mn^II complex incorporating chloride and 2,5-bis­(2,2′-bipyridyl-6-yl)-3,4-di­aza­hexa-2,4-diene ligands.