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2,2'-Disulfanyl­idene-5,5'-biimidazolidinyl­idene mol­ecules aggregate through N-H...S hydrogen-bonding inter­actions with cyclic motifs [graph set R_{2}^{2}(8)], giving two-dimensional ribbon structures which are close to being parallel. Two independent water mol­ecules associate to form centrosymmetric cyclic hydrogen-bonded (H2O)4 tetra­mer units [graph set R_{4}^{4}(8)].
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