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A one-dimensional polymeric structure of CoII with sulfadiazine and 1,3-bis­(pyridin-4-yl)propane is further stabilized by inter­molecular hydrogen bonding. The structure is of inter­est with respect to its electrochemical properties in the reduction reaction of H2O2 to H2O. Investigation of the thermal stability shows that the complex is stable up to 543 K.

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A one-dimensional polymeric structure of CdII with sulfaquinoxaline is further stabilized by inter­molecular hydrogen bonding. The fluorescence spectrum reveals that the complex emits strong blue fluorescence. The thermal analysis shows that the framework is stable up to 663 K.
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