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The tridentate Schiff base ligand 2,4-dihydroxy­acetophenone salicylhydrazide, derived from the condensation of 2,4-dihydroxy­acetophenone and salicylhydrazide, in the presence of pyridine and N,N′-dimethyl­formamide, forms a dinuclear distorted square-pyramidal Zn complex with Zn(OAc)2·2H2O, viz. [Zn2(C15H12N2O4)2(C5H5N)2]·2C3H7NO. The complex is centrosymmetric and the two Zn atoms are bridged by two phenolate O atoms.
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