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In the cation of the title compound, C20H26N22+·2Cl-·CH4O, there is an approximate twofold rotation axis. All the four chiral centers are in the S configuration. All three six-membered rings in the central part of the cation adopt a boat conformation. Both chloride anions and the O atom in the solvent mol­ecule form hydrogen bonds with the cation, resulting in a chain along [010].
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