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The title compound, C18H17BrO8, was synthesized in an anhydrous medium at 293 K. The dihedral angle between the two benzene rings is 38.8 (2)°.

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The title compound, C18H27N3O3S, is an organocatalyst prepared from (1R,2R)-cyclo­hexa­ne-1,2-diamine. There are bifurcated N—H...N/O intra­molecular hydrogen bonds and N—H...O and C—H...O inter­molecular inter­actions.
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