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The title compound, C9H8N6OS, crystallizes with two mol­ecules in the asymmetric unit. In the crystal structure, intermolecular N—H...N hydrogen bonds form a three-dimensional network.

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The title compound, C10H8N4S4, displays an approximate symmetry that closely fits the C2h point group, but it crystallizes in a general position without crystallographic symmetry. The crystal structure is stabilized by two inter­molecular C—H...N close contacts.
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