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In the title compound, C11H10Cl2O3, the six-membered heterocyclic ring adopts a half-chair conformation. An inter­molecular C—H...O hydrogen bond and π–π stacking are observed in the crystal structure.

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In the crystal structure of the title compound, C10H11NO4, O—H...O inter- and intramolecular hydrogen bonds are present, as well as intermolecular C—H...O interactions.

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In the title compound, C17H18N4O3, which displays good herbicidal activity, the planar bicyclic triazolopyrimidine system is bound to the benzoic acid isoprop­yl ester moiety via an O bridge. The dihedral angle formed by the bicylic triazolopyrimidine system and the benzene ring is 106.2 (2)°. Neither intra- nor inter­molecular hydrogen bonds are found.

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The crystal structure of the title compound, C21H19Cl2NO3·H2O, shows that there are no intra- or inter­molecular π—π stacking inter­actions. The structure is stabilized by O—H...O hydrogen bonds involving the carbon­yl group and the solvent water mol­ecule.

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In the crystal structure of the title compound [systematic name: N-(2,6-difluoro­phen­yl)-5-meth­yl-1,2,4-triazolo[1,5-a]pyrimidine-2-sulfonamide acetonitrile solvate], C12H9F2N5O2S·C2H3N, the planar bicyclic triazolopyrimidine system is bound to the 2,6-difluoro­benzene group via an SO2–NH bridge, the C—S—N—C torsion angle being −77.85 (18)°; the dihedral angle formed by the bicyclic triazolopyrimidine system and the benzene ring is 128.0 (2)°. N—H...N bonds link the mol­ecules into infinite chains running along the a axis of the crystal structure.

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The mol­ecular structure of the title compound, C19H14ClNO3S, contains a 4-oxothia­zolidine ring in a near planar geometry.

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The crystal structure of the title compound, C21H17Cl2NO3, shows that there are no intra- or inter­molecular π–π stacking inter­actions. The structure is stabilized by C—H...O and C—H...Cl hydrogen bonds, which form a nine-membered ring.

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In the title compound, C16H16N4O3, which displays good herbicidal activity, the planar bicyclic triazolopyrimidine system is bound to an ethyl benzoate moiety via an oxo bridge, with a dihedral angle of 73.98 (2)° between the bicylic triazolopyrimidine system and the benzene ring. In the crystal structure, mol­ecules are linked by inter­molecular C—H...O hydrogen bonds and π–π stacking inter­actions between the triazolopyrimidine rings.
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