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organic compounds
The title compound, C12H16N4OS, is zwitterionic and exists in the EZ configuration of thiosemicarbazones. The thiocarbonyl S atom and coordinating pyridyl N atom are aligned cis to each other, avoiding the possibility of a structural reorientation upon coordination. Two crystallographically independent molecules, A and B, are observed in the asymmetric unit, with the morpholyl ring adopting a chair conformation in both molecules. N—H
N and N—HS intramolecular hydrogen bonds are observed in the molecular structure, generating four rings of motif R12(5). There is zigzag packing in the unit cell, involving both intra- and intermolecular hydrogen-bonding interactions.
N and N—HS intramolecular hydrogen bonds are observed in the molecular structure, generating four rings of motif R12(5). There is zigzag packing in the unit cell, involving both intra- and intermolecular hydrogen-bonding interactions.organic compounds
The title compound, C6H8N4S, crystallizes as the thione tautomer, with intramolecular NH—N and SH—N hydrogen bonds, and π–π stacking along the b axis. Intermolecular NH—N hydrogen bonds link the molecules into one-dimensional sheets stacked along the c axis.
H—N and SH—N hydrogen bonds, and π–π stacking along the b axis. Intermolecular NH—N hydrogen bonds link the molecules into one-dimensional sheets stacked along the c axis.
