metal-organic compounds
In the crystal structure of the title compound, [Zn(NCS)2(C6H8N2)2], the Zn atom and both isothiocyanate groups lie on a crystallographic mirror plane. The Zn atom is in a distorted tetrahedral geometry. The crystal structure is stabilized by N—HS hydrogen bonds and weak π–π interactions.
metal-organic compounds
In the centrosymmetric title compound, [Cd(NCS)2(C6H8N2)4], the CdII atom is in a distorted octahedral environment. The crystal structure is stabilized by N—HS hydrogen bonds and weak N—Hπ and C—Hπ interactions.