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The title compound, C10H9N5O2·C2H6O, was synthesized by the reaction of 3-hydrazino-1H-1,2,4-triazole with 2-hydroxy­benz­aldehyde in ethanol. The crystal structure involves intermolecular O—H...O, N—H...O and N—H...N hydrogen bonds; intramolecular O—H...N and N—H...N hydrogen bonds are also found.

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The title compound, C20H18N4O2·2H2O, an amide-containing bipyridyl-type compound, crystallizes as a dihydrate. The organic molecule is centrosymmetric. Hydro­gen-bonding and π–π stacking interactions in the crystal structure result in the formation of an infinite three-dimensional supramolecular network.

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In the crystal structure of the title compound, C10H9N5O2, inter­molecular N—H...N [H...N = 2.13 (2) Å] and N—H...O [H...O = 2.016 (18) and 2.05 (2) Å] hydrogen bonds link mol­ecules into a two-dimensional framework.
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