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In the title compound, C9H11NOS, the phenyl ring and formamide unit make a dihedral angle of 23.93 (14)°, whereas the (methylsulfanyl)methyl group is oriented at a dihedral angle of 61.31 (8)° with respect to the phenyl ring. There are intermolecular N—H
O hydrogen bonds, forming C(4) chains along the [010] direction. These polymeric chains are linked by C—HO hydrogen bonds to form polymeric sheets in the (110) plane.
O hydrogen bonds, forming C(4) chains along the [010] direction. These polymeric chains are linked by C—HO hydrogen bonds to form polymeric sheets in the (110) plane.organic compoundsOpen access
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In the title compound, C16H14Cl2O3, the dihedral angle between the mean planes of the two benzene rings is 55.30 (5)°. The methyl ester group lies within the ring plane due to an intramolecular O—HO hydrogen bond [maximum deviation from the C8O2 mean plane is 0.0383 (13) Å]. In the crystal, molecules are held together by rather weak C—HO hydrogen bonds.
O hydrogen bond [maximum deviation from the C8O2 mean plane is 0.0383 (13) Å]. In the crystal, molecules are held together by rather weak C—HO hydrogen bonds.organic compoundsOpen access
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In the title compound, C11H7ClFN, the chlorobenzene and 2-fluoropyridine rings are oriented at a dihedral angle of 38.83 (5)°. In the crystal, there are no hydrogen-bonding interactions.
organic compoundsOpen access
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In the title compound, C11H7F2N, the fluorobenzene and the 2-fluoropyridine rings are oriented at a dihedral angle of 37.93 (5)°. In the crystal, only van der Waals interactions occur.
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In the title compound, C11H8FNO, the aromatic rings are oriented at a dihedral angle of 31.93 (6)°. In the crystal, molecules are linked by O—HN hydrogen bonds, forming C(9) chains propagating along the c-axis direction. There are aromatic π–π stacking interactions between the pyridine rings [centroid–centroid separation = 3.7238 (16) Å].
N hydrogen bonds, forming C(9) chains propagating along the c-axis direction. There are aromatic π–π stacking interactions between the pyridine rings [centroid–centroid separation = 3.7238 (16) Å].organic compoundsOpen access
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In the title compound, C11H6Cl2FN, the dichlorobenzene and the 2-fluoropyridine rings are oriented at a dihedral angle of 47.73 (3)°. In the crystal, pairs of C—HN interactions link the molecules into dimers with R22(12) motifs. Molecules are arranged in stacks extending along [100] via π–π interactions with a centroid–centroid distance of 3.8889 (3) Å.
N interactions link the molecules into dimers with R22(12) motifs. Molecules are arranged in stacks extending along [100] via π–π interactions with a centroid–centroid distance of 3.8889 (3) Å.organic compoundsOpen access
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In the title compound, C12H9BrFNO, the dihedral angle between the aromatic rings is 51.39 (5)°; the C atom of the methoxy group is close to being coplanar with its attached ring (r.m.s. deviation = 0.0172 Å] and is oriented away from the pyridine ring. In the crystal, molecules interact by van der Waals forces.
