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The title compound, penta­barium tris­(vanadate) chloride, crystallizes in the well known apatite structure type, with space group P63/m and Z = 2. The crystal structure contains isolated (VO4)3- tetra­hedra that are bridged by Ba2+ ions. The inter­mediate Cl- anions, situated on positions with \overline{3} symmetry, are octa­hedrally surrounded by Ba2+ cations.
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