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The framework of the title compound is made up of discrete Mg(H2O)6 octa­hedra, and HPO3 and NH4 tetra­hedra, which are organized in planes parallel to (010). Strong hydrogen bonding between the building units stabilizes the structure. The hydrogenphosphate(III) tetra­hedra, the ammonium tetra­hedron and one of the two Mg atoms lie on positions with m symmetry, whereas the second Mg atom is located on a position with 2/m symmetry.
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