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The structure of cerium diruthenium decaaluminium, CeRu2Al10, is characterized by seven crystallographic sites in space group Cmcm, viz. Ce in 4c, Ru in 8a, two Al atoms in 8g, two Al atoms in 8f and one Al atom in 8e. The structure can be interpreted as a stacking of alternating columns running along [001], each formed by only one type of Ru cuboid with composition RuAl6 or CeRuAl4.

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The title compound, C7H9N4O+·Cl, was obtained as a product of the thermal decomposition of nimustine hydro­chloride (ACNU). In the crystal structure, intermolecular N—H...O hydrogen bonds link the cations into centrosymmetric dimers, which are further connected by N—H...Cl and C—H...Cl hydrogen bonding to form two-dimensional networks.
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