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In the crystal structure of the title compound, [Zn(NCS)2(C12H10ClN)2], the Zn2+ cation is N-coordinated by two terminally bonded thio­cyante anions and by two 4-(4-chloro­benz­yl)pyridine ligands within a slightly distorted tetra­hedron. The asymmetric unit consists of half of the discrete complex, the central Zn2+ cation of which is located on a twofold rotation axis. The discrete complexes are linked into layers via a weak inter­molecular hydrogen-bonding inter­action, with a H...Cl distance of 2.85 Å and a C—H...Cl angle of 151°. These layers extend parallel to the ab plane and are held together by dispersion forces only.

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In the crystal structure of the title compound, [Cd(NCS)2(C9H13N)2]n, the CdII cations are coordinated in a slightly distorted octa­hedral geometry by one 3-tert-butyl­pyridine ligand, one 4-tert-butyl­pyridine ligand and two pairs of translationally-equivalent μ-1,3-bridging thio­cyanate ligands, all of which are in general positions. These μ-1,3-bridging thio­cyante anions bridge the CdII cations, forming chains that propagate parallel to the b axis.
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