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In the mononuclear title salt, [Ag(C3H8N2S)(C18H15P)3](CH3COO), the AgI ion exhibits a distorted tetrahedral coordination sphere defined by three P atoms from three triphenylphosphane ligands and one S atom from a 1,3-dimethylthiourea ligand. In the crystal, the acetate anion is linked with the complex cation via duplex N—HO hydrogen bonds [graph-set motif R22(8)].