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In the crystal structure of the title compound, (C3H11NOP)2[PdCl4], (di­methyl­phosphor­yl)methanaminium (dpmaH+) cations are connected head-to-tail by strong N—H...O hydrogen bonds, forming inversion-related cyclic dimers. The square-planar [PdCl4]2− counter-dianion is located about a center of inversion. The dications and the [PdCl4]2− dianions are connected by medium–strong N—H...Cl hydrogen bonds, forming zigzag chains parallel to [001]. Somewhat weaker N—H...Cl hydrogen bonds connect the chains into a three-dimensional network.

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In the crystal of the title salt, C3H11NOP+·NO3, dicationic inversion dimers are head-to-tail connected by a pair of strong N—H...O hydrogen bonds. The resulting graph-set descriptor of this ring system is R22(10). The nitrate counter-anions connect the dicationic dimers via N—H...O hydrogen bonds, forming two-dimensional networks in the bc plane.
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