inorganic compounds
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The title compound, Li2[Sn(OH)6]·2H2O, is dimorphic. As for the previously described α-modification, the title β-modification crystallizes in the monoclinic system and contains the same primary building units, viz [Sn(OH)6]2− octahedra and [Li(μ2-OH)3(H2O)] tetrahedra. In contrast to the Sn—O bond lengths that are very similar in both modifications, the Li—O bond lengths differ significantly, in particular those involving the water molecule. In the new β-modification, the primary building units are linked into layers parallel to (010). The [Sn(OH)6]2− octahedra (-1 symmetry) form hexagonal nets and the [Li(μ2-OH)3(H2O)] tetrahedra are situated in between, with their apices in an alternating fashion up and down. O—HO hydrogen bonds between OH groups and water molecules exist within the layers as well as between them.