metal-organic compounds
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In the title compound, {(NH4)2[Zn(C8H6O8)]·4H2O}n, the asymmetric unit contains one ammonium cation, half of a butane-1,2,3,4-tetracarboxylate anion, one Zn2+ cation and two water molecules. The butane-1,2,3,4-tetracarboxylate ligand is located about an inversion centre at the mid-point of the central C—C bond. The Zn2+ cation is situated on a twofold rotation axis and is surrounded by four O atoms from four symmetry-related butane-1,2,3,4-tetracarboxylate anions in a distorted tetrahedral environment. In turn, each anion coordinates to four Zn2+ cations. The bridging mode of the anions leads to a three-dimensional framework structure with channels extending along [110] and [010] in which the ammonium cations and the water molecules are located. N—HO and O—HO hydrogen bonding between the cations and water molecules and the uncoordinating O atoms of the carboxylate groups consolidates the crystal packing.
organic compounds
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In the title compound, C10H9NO3, the dihedral angle between the phenyl ring and the amide group is 10.8 (2)°. The C=O and O—H bonds of the carboxyl group adopt an anti orientation and an intramolecular O—HO hydrogen bond closes an S(7) ring. In the crystal, N—HO hydrogen bonds link the molecules into C(7) chains propagating in [101]. The packing is consolidated by C—HO interactions, generating sheets aligned at an angle of ca 60° with the bc plane.
organic compounds
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During the recrystallization of 3-[4-(2-carboxyethyl)piperazin-1-yl]propionic acid, the carboxylic acid H atoms were transferred to the piperazine N atoms, forming the title compound, C10H18N2O4·2H2O, in which the zwitterion lies about an inversion center. In the crystal, bifurcated N—H(O,O) hydrogen bonds connect the zwitterions into a two-dimensional framework parallel to (-102) forming R44(30) rings. O—HO hydrogen bonds involving the solvent water molecules connect the two-dimensional framework into a three-dimensional network. In addition, weak C—HO hydrogen bonds are observed.
organic compounds
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In the title compound, C10H14N4·0.5H2O, the amino H atom of one of the two pyrazole rings is disordered over its two N atoms in a 1:1 ratio. The pyrazole rings are aligned at 60.1 (1)°. In the crystal, two bipyrazolyl molecules are linked by an N—HN hydrogen bond, generating a dimer; the dimer is connected to the water molecule, which lies on a twofold rotation axis, resulting in the formation of a chain that makes an angle of ca 45.3 (1)° with the ab plane. The chains are cross-linked by N—HO and O—HN interactions, forming a three-dimensional network.
organic compounds
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In the title molecular salt, C5H9N2+·C7H3N2O7−, the roughly planar anion (r.m.s. deviation = 0.120 Å) has been deprotonated at the phenol group. An intramolecular O—HO hydrogen bond in the anion generates an S(6) ring. In the crystal, the components are linked by cation-to-anion N—HO and N—H(O,O) hydrogen bonds, generating [010] double chains. Weak C—HO interactions consolidate the packing.