metal-organic compounds
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Redetermination of (acetonitrile-κN)dicarbonyl(η5-cyclopentadienyl)iron(II) tetrafluoridoborate
The crystal structure of the title compound, [Fe(C5H5)(CH3CN)(CO)2]BF4, of which only the coordinates of the non-H atoms of the cation have previously been reported [Fadel et al. (1979). Z. Anorg. Allg. Chem. 453, 98–106] has been redetermined. The FeII atom in the complex cation is coordinated by a cyclopentadienyl ring, two carbonyl ligands and an acetonitrile molecule displaying a three-legged piano stool structure. Three of the four F atoms of the BF4− anion are disordered over two sets of sites, with a site-occupancy factor of 0.709 (10) for the major occupied site.