Download citation
Download citation

link to html
In the structure of the title compound, [Cu(C14H11N3OS)(C5H5N)], the CuII atom exhibits a slightly distorted square-planar CuN2OS coordination polyhedron consisting of a phenyl O, an azomethine N and a thio­amide S atom from the tridentate thio­semicarbazonate dianion, and the N atom of a pyridine mol­ecule. The thio­semicarbazonate ligand exists in the thiol tautomeric form as an E isomer. Rotational disorder of the pyridine and phenyl rings in a 1:1 ratio of the respective components is observed. An extensive network of weak N—H...S, C—H...O, C—H...N and C—H...S hydrogen-bonding inter­actions consolidates the structure.
Follow Acta Cryst. E
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds