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The structure of the title compound, C6H10N2O, has been determined from single crystals obtained by recrystallization from acetone. Intermolecular O—H...N hydrogen bonding gives rise to R22(10) dimers.

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The crystal structure of the title compound, [Cd2Cl4(C6H9N3S)2], has been determined. The compound is isomorphous with the previously reported CuII and CoII complexes. It is centrosymmetric and contains binuclear molecular units with five-coordinate Cd atoms, doubly bridged by Cl atoms. The structure is stabilized by a two-dimensional network of hydrogen bonds involving the terminal Cl atoms as acceptors and thio­carbamoyl group N atoms as donors.
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