metal-organic compounds
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In the title compound, (C8H12N)3[Sb2Br9], two of the three unique N,N-dimethyanilinium cations exhibit flip–flop disorder with an occupancy ratio of 0.58 (1):0.42 (1). N—HBr hydrogen bonds link the organic cations and bioctahedral face-sharing anions into a three-dimensional network.