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The title complex, [Nd2(C8H3NO6)2(C8H4NO6)2(H2O)6]·2H2O, consists of dimeric units related by an inversion center. The NdIII atom is nine-coordinated by three O atoms from water mol­ecules and six from carboxyl­ate atoms. The 1,2-dicarboxylate acid molecules are in a single and double deprotonation stage and exhibit two coord­in­ation modes, viz. μ2-(κ4, O1: O2: O2: O3) and μ1-(κ2, O2: O3), which are responsible for the dimeric structure framework. The dimeric structure is then assembled into a three-dimensional supramolecular framework via O—H...O hydrogen bonds.
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