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In the cation of the title salt, [Ag(C12H6N2O2)2](C7H3N2O7), the AgI atom is coordinated in a distorted tetra­hedral geometry by four N atoms from two 1,10-phenanthroline-5,6-dione ligands, while the 3,5-dinitro­salicylate anion has only a short contact [2.847 (6) Å] between one of its O atoms and the AgI atom. The dihedral angle between the two 1,10-phenanthroline-5,6-dione ligands is 58.4 (1)°. There is an intra­molecular O—H...O hydrogen bond in the 3,5-dinitro­salicylate anion.

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In the crystal structure of the title compound, C18H13N5·H2O, adjacent mol­ecules are linked by O—H...N and N—H...O hydrogen bonds, generating a chain propagating along [001].
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