metal-organic compounds
Open access
In the title mononuclear complex, [CoCl2(C11H11N5)2], the CoII atom is four-coordinated by two ligand N atoms and two Cl atoms in a distorted tetrahedral geometry. In the crystal, molecules are stacked through π–π interactions [centroid–centroid distances = 3.473 (2), 3.807 (3), 3.883 (2) and 3.676 (2) Å], forming a three-dimensional supramolecular network.
organic compounds
Open access
The title compound, C23H19BrO2, was synthesized from 13-bromo-4-hydroxy[2.2]paracyclophane and benzoyl chloride. The hydroxy and carbonyl groups are involved in intramolecular O—HO hydrogen bonding. The crystal packing exhibits weak C—HO interactions, which link the molecules into sheets parallel to the bc plane.