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The crystallographic analysis of the title compound, C12H28N+·ClO4, (I), shows that inter­molecular C—H...O inter­actions stabilize the crystal structure. The compound is isomorphous with tetra-n-propyl­ammonium iodide, whose structure has been described by Yoshida et al. [Acta Cryst. (1994). C50, 1758–1760].

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The title compound, C28H44N2, is one of the precursors of the amphiphilic heteroleptic ruthenium(II) sensitizer for DSC (dye-sensitized solar cells), and its molecule has a crystallographically imposed centre of symmetry. A segregated packing structure between the alk­yl chain layers and pyridine rings is observed.
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