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In the title complex, [Ni(C3H7NO)2(C9H20N2S2)](C24H20B)2·2CH3CN, the metal centre has a distorted octahedral environment, with four coordination sites occupied by two N- and two S-donor atoms from a 3-amino­propyl pendant arm derivative of the nine-membered macrocycle 1-aza-4,7-di­thia­cyclo­nonane, and the remaining two positions by two mutually cis di­methyl­form­amide ligands.
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