metal-organic compounds
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In the title complex, [Ni(C3H7NO)2(C9H20N2S2)](C24H20B)2·2CH3CN, the metal centre has a distorted octahedral environment, with four coordination sites occupied by two N- and two S-donor atoms from a 3-aminopropyl pendant arm derivative of the nine-membered macrocycle 1-aza-4,7-dithiacyclononane, and the remaining two positions by two mutually cis dimethylformamide ligands.