3-(Di­phenyl­amino)­isobenzo­furan-1(3H)-one

In the title isobenzo­furan­one derivative, C₂₀H₁₅NO₂, the planar fused-ring system (r.m.s. deviation for the 10 fitted atoms = 0.031 Å) forms dihedral angles of 63.58 (6) and 63.17 (8)° with the N-bound phenyl rings; the dihedral angle between the planes of these phenyl rings is 85.92 (7)°. In the crystal, mol­ecules are linked by weak C—H...O inter­actions, involving both O atoms, forming helical supra­molecular chains along [001].

Crystal structure of (±)-3-[(benzo[d][1,3]dioxol-5-yl)meth­yl]-2-(3,4,5-tri­meth­oxy­phen­yl)-1,3-thia­zolidin-4-one

In the title thia­zolidine-4-one derivative, C₂₀H₂₁NO₆S, the central thia­zolidine ring is essentially planar (r.m.s. deviation for all non-H atoms = 0.0287 Å) and forms a dihedral angle of 88.25 (5)° with the meth­oxy-substituted benzene ring and 74.21 (4)° with the 1,3-benzodioxole ring. The heterocyclic ring (with two O atoms) fused to benzene ring adopts an envelope conformation with the non-ring-junction C atom as the flap. In the crystal, the mol­ecules are linked into chains along [001] through weak C—H...O inter­actions, forming R⁴₄(28) edge-fused rings.