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metal-organic compounds
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In the title compound, [Ru2(C10H14)2Cl2(C16H8N4)](PF6)2·2C3H6O, the binuclear RuII complex dication, [{RuCl(η6-cym)}2(μ-tape)]2+, built up by a planar 1,6,7,12-tetraazaperylene (tape) bridge, two η6-bound cymene (cym) ligands and two chloride ligands, includes an inversion center. The RuII atom shows the typical piano-stool motif for arene coordination. The counter-charge is provided by a hexafluoridophosphate anion and the asymmetric unit is completed by an acetone molecule of crystallization. The components of the structure are connected into a three-dimensional architecture by C—H
O/F/Cl interactions.
O/F/Cl interactions.metal-organic compoundsOpen access
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In the title compound, rac-[Ru(C14H16N2)2(C16H8N4)](PF6)2·3C2H3N, discrete dimers of complex cations, [Ru(tmbpy)2tape]2+, of opposite chirality are formed (tmbpy = tetramethylbipyridine; tape = tetraazaperylene), held together by π–π stacking interactions between the tetraazaperylene moieties with centroid–centroid distances in the range 3.563 (3)–3.837 (3) Å. These interactions exhibit a parallel displaced π–π stacking mode. Additional weak C—Hπ-ring and C—HN and C—HF interactions are found, leading to a three-dimensional architecture. The RuII atom is coordinated in a distorted octahedral geometry. The counter-charge is provided by two hexafluoridophosphate anions and the asymmetric unit is completed by three acetonitrile solvent molecules of crystallization. Four F atoms of one PF6− anion are disordered over three sets of sites with occupancies of 0.517 (3):0.244 (3):0.239 (3). Two acetonitrile solvent molecules are highly disordered and their estimated scattering contribution was subtracted from the observed diffraction data using the SQUEEZE option in PLATON [Spek (2009). Acta Cryst. D65, 148–155].
π-ring and C—HN and C—HF interactions are found, leading to a three-dimensional architecture. The RuII atom is coordinated in a distorted octahedral geometry. The counter-charge is provided by two hexafluoridophosphate anions and the asymmetric unit is completed by three acetonitrile solvent molecules of crystallization. Four F atoms of one PF6− anion are disordered over three sets of sites with occupancies of 0.517 (3):0.244 (3):0.239 (3). Two acetonitrile solvent molecules are highly disordered and their estimated scattering contribution was subtracted from the observed diffraction data using the SQUEEZE option in PLATON [Spek (2009). Acta Cryst. D65, 148–155].
