Tri-μ-chlorido-bis­[(η⁵-penta­methyl­cyclo­penta­dien­yl)rhodium(III)] hexa­fluorido­phosphate from synchrotron radiation

In the title complex salt, [{(η⁵-C₅Me₅)Rh}₂(μ-Cl)₃]PF₆, the dinuclear, single-charged cation is formed by the cojoining of two classic (η⁵-C₅Me₅)RhCl₃ `piano-stool' units by bridging of the three choride ligand `legs'. The crystal structure shows several close H...F contacts between the hexa­fluorido­phosphate counter-ions and the C₅Me₅ ligands.