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The asymmetric unit of the title salt, C3H7N6+·C6H7O4·C3H4O2·H2O, contains a 2,4,6-tri­amino-1,3,5-triazin-1-ium cation, a 3-(prop-2-eno­yloxy)propano­ate anion and acrylic acid and water solvent mol­ecules in a 1:1:1:1 ratio and with each species in a general position. In the crystal, the components are linked into a supra­molecular layer in the bc plane via a combination of O—H...O, N—H...N and N—H...O hydrogen bonding. The crystal studied was a non-merohedral twin, the minor component contribution being approximately 26%.

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The asymmetric unit of the title compound, C3H6N6·2C6H5NO3, contains one melamine and two 3-nitro­phenol mol­ecules. The mean planes of the 3-nitro­phenol mol­ecules are almost orthogonal to the plane of melamine, making dihedral angles of 82.77 (4) and 88.36 (5)°. In the crystal, mol­ecules are linked via O—H...N, N—H...N and N—H...O hydrogen bonds, forming a three-dimensional network. The crystal also features weak C—H...π and π–π inter­actions [centroid–centroid distance = 3.9823 (9) Å].
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