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The binuclear title complex, [Co2(C18H26N4O12)(H2O)2]·4H2O, lies about a centre of inversion, the CoII atom being coordinated in a distorted octa­hedral arrangement defined by one water mol­ecule and N2O3 donors derived from one end of a 6,9-bis(carboxylatomethyl)-3,12-bis(car­boxy­methyl)-3,6,9,12-tetraaza­tetradecanedioate (H2TTHA4−) tetra­anion. In the crystal, numerous O—H...O hydrogen bonds link the mol­ecules into a three-dimensional network.
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