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The SmIII ion in the title compound, [SmCl3(C12H10N2O)3], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl3N6 donor set. The mol­ecular structure is stabilized by three intra­molecular O—H...Cl hydrogen bonds.

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In the title compound, C20H20N2, the quinoxaline ring adopts a very distorted half-chair conformation [N=C-C=N = 22.7 (2)° for the nominally coplanar atoms] and the cyclo­hexane ring adopts a chair conformation. The quinoxaline and cyclo­hexane rings are cis-fused. The two phenyl rings form a dihedral angle of 63.88 (7)°.
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