Potassium morpholine-4-carbodithio­ate monohydrate. Corrigendum

Corrigendum to Acta Cryst. (2012), E68, m1025 .

μ-Azido-κ²N¹:N¹-μ-chlorido-bis­[(2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl-κ²C¹,N)palladium(II)] chloro­form monosolvate

In the binuclear title complex, [Pd₂(C₁₁H₁₃ClN)₂Cl(N₃)]·CHCl₃, each Pd^II atom has a slightly distorted square-planar geometry being coordinated by a C and an N atom of the 2-chloro-3-dimethyl­amino-1-phenyl­propyl ligand, a bridging Cl atom and an N atom of a bridging end-on azide group. There is a short intra­molecular C—H...Cl contact in the complex mol­ecule. In the crystal, the chloro­form solvent mol­ecule is linked to the complex via a C—H...π inter­action.

(Benzyl isocyanide-κC¹)chlorido(2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl-κ²C¹,N)palladium(II)

In the title compound, [Pd(C₁₁H₁₃ClN)Cl(C₈H₇N)], which crystallized in the chiral space group P2₁2₁2₁, the Pd^II atom is coordinated by two C atoms, a Csp² atom of the 2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well as an N atom of the ligand and a Cl atom, in a square-planar geometry. In the complex, there is a short C—H...Cl hydrogen bond and a C—H...π inter­action. In the crystal, mol­ecules are linked via C—H...Cl hydrogen bonds, forming chains along the a-axis direction.

2-({1-[2-(Methyl­sulfan­yl)phen­yl]-1H-tetra­zol-5-yl}sulfan­yl)acetic acid

In the title compound, C₁₀H₁₀N₄O₂S₂, the tetra­zole and benzene rings are almost normal to one another, with a dihedral angle between their planes of 84.33 (9)°. In the crystal, mol­ecules are linked via pairs of bifurcated O—H...(N,N) hydrogen bonds, forming inversion dimers with graph-set motif R₄⁴(12). The dimers are linked by significant π–π inter­actions involving inversion-related tetra­zole rings and inversion-related benzene rings, with centroid–centroid distances of 3.7376 (14) and 3.8444 (15) Å, respectively.

4-{5-[(2-Bromo­benz­yl)sulfan­yl]-1H-tetra­zol-1-yl}benzoic acid

In the title compound, C₁₅H₁₁BrN₄O₂S, the tetra­zole ring makes dihedral angles of 45.97 (10) and 75.41 (1)°, respectively, with the benzoyl and bromo­benzene rings while the dihedral angle between the benzene rings is 73.77 (1)°. In the crystal, mol­ecules are linked through O—H... N and C—H... O hydrogen bonds, giving infinite chains in both the [110] and [1-10] directions. These chains are further connected by C—Br...π and C—O...π inter­actions and also by π–π stacking between tetra­zole rings [centroid–centroid distance = 3.312 (1) Å], generating a three-dimensional network.