organic compounds
The title compound, C16H9ClF2N4S, was prepared by the reaction of 4-amino-5-mercapto-3-chlorophenyl-1,2,4-triazole and 2-bromo-2',4'-fluoroacetophenone. The six-membered thiadiazine ring is distorted from planarity, with an r.m.s. deviation of 0.201 Å. All C and N atoms of the triazole ring are conjugated.