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The polymeric title mol­ecule, {[Ni2(C8H7O2)4(C10H8N2)3(H2O)2]·2H2O}n, lies on a center of symmetry at the mid-point of the Cpyridine—Cpyridine bond of one of the two 4,4′-bipyridine mol­ecules that link the adjacent aqua­nickel(II)–dicarboxyl­ate units into a linear chain. The other 4,4′-bipyridine mol­ecule connects adjacent chains into a square (C10H8N2)3Ni2 grid. The ladder-like layer structure is disordered in all the organic groups bonded to the metal atom; the uncoordinated water mol­ecules inter­act within the layers through hydrogen bonds.
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