metal-organic compounds
The polymeric title molecule, {[Ni2(C8H7O2)4(C10H8N2)3(H2O)2]·2H2O}n, lies on a center of symmetry at the mid-point of the Cpyridine—Cpyridine bond of one of the two 4,4′-bipyridine molecules that link the adjacent aquanickel(II)–dicarboxylate units into a linear chain. The other 4,4′-bipyridine molecule connects adjacent chains into a square (C10H8N2)3Ni2 grid. The ladder-like layer structure is disordered in all the organic groups bonded to the metal atom; the uncoordinated water molecules interact within the layers through hydrogen bonds.