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In the crystal structure of the title salt, C4H6N3O+·HSeO3, systematic name 6-amino-2-methyl­idene-2,3-di­hydro­pyrim­idin-1-ium hydrogen selenite, the hydrogenselenite anions and the cytosinium cations are linked via N—H...O, N—H...Se, O—H...O, O—H··Se and C—H...O hydrogen bonds, forming a three-dimensional framework.

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The asymmetric unit of the title compound, [Cu(C2H8N2)2(H2O)2](C11H11N4O2S)2, contains one sulfamerazinate anion in a general position and one half-cation that is located on a center of inversion. The CuII cation shows a strong Jahn–Teller distortion. It is coordinated by four N atoms of two ethyl­enedi­amine ligands in the basal plane and two O atoms at much longer distances in the axial positions in a bipyramidal coordination. In the crystal, the building blocks are connected by N—H...N, O—H...N, N—H...O and O—H...O hydrogen bonding into a two-dimensional network parallel to (001).
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