organic compounds
Open access
In the title compound, C9H10N4OS, the dihedral angle between the benzene and 1H-1,2,4-triazole-5(4H)-thione rings is 67.51 (16)°. In the crystal, molecules are liked via N—HO hydrogen bonds, forming chains along the c-axis direction. The chains are linked via O—HS hydrogen bonds, forming corrugated layers lying parallel to the bc plane. The layers are linked via N—HN and N—HS hydrogen bonds, forming a three-dimensional network.
organic compounds
Open access
In the title compound, C10H9ClN4S, the dihedral angle between the mean planes of the phenyl and 1H-1,2,4-triazole-5(4H)-thione rings is 25.3 (9)°. The latter ring is essentially planar, with maximum deviations of 0.010 and −0.010 Å for the ring N atom in the 4-position and ring C atom bearing the methyl group, respectively. An intramolecular C—HS contact occurs. In the crystal, pairs of weak N—HS interactions link the molecules into inversion dimers in the ac plane, forming R22(8) graph-set motifs. In addition, weak π–π interactions [centroid–centroid distances = 3.3463 (14) and 3.6127 (13)Å] are observed.