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In the title compound, C23H15F3N2O2S, the thiazole ring makes dihedral angles of 12.98 (13), 49.30 (11) and 49.83 (12)° with the pyridine ring, the methoxyphenyl ring and the (trifluoromethyl)phenyl ring, respectively. In the crystal, molecules are connected via C—H
O hydrogen bonds, forming chains along [010]. There are also C—Hπ and C—Fπ interactions present, forming a three-dimensional structure.
O hydrogen bonds, forming chains along [010]. There are also C—Hπ and C—Fπ interactions present, forming a three-dimensional structure.organic compoundsOpen access
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In the title compound, C23H20F3N3O3S2, the benzoimidazole unit makes dihedral angles of 5.02 (1) and 76.42 (1)°, respectively, with the pyridine and methylbenzene rings; the dihedral angle between the pyridine and methylbenzene rings is 72.19 (1)°. In the crystal, molecules are connected by weak C—HF, C—HO and C—HN hydrogen bonds. Weak C—Hπ interactions and π–π stacking [centroid–centroid distance = 3.6485 (14) Å] are also observed. The overall packing shows a three-dimensional architecture. The crystal structure contains a void of 51 Å3, but no solvent molecule (hexane or ethyl acetate) is located within it.
F, C—HO and C—HN hydrogen bonds. Weak C—Hπ interactions and π–π stacking [centroid–centroid distance = 3.6485 (14) Å] are also observed. The overall packing shows a three-dimensional architecture. The crystal structure contains a void of 51 Å3, but no solvent molecule (hexane or ethyl acetate) is located within it.
