metal-organic compounds
Open access
The whole molecule of the title compound, [NiCl2(C3H4N2)2(NH3)2], is generated by inversion symmetry. The NiII ion, which is located on an inversion center, has a distorted octahedral coordination environment and is surrounded by two ammine N atoms and two Cl atoms in the equatorial plane, with two N atoms of two imidazole groups occupying the axial positions. The imidazole ring makes a dihedral angle of 81.78 (18)° with the Ni/N/Cl equatorial plane. In the crystal, molecules are linked via N—HCl hydrogen bonds and C—Hπ interactions, forming a three-dimensional network.
metal-organic compounds
Open access
In the title compound, [Ni(C7H12N2)4(H2O)2]Cl2, the nickel(II) ion has a distorted octahedral coordination environment. It is surrounded by three N atoms and one O atom occupying the equatorial plane, and one N and one O atom in the axial positions. The imidazole ring systems are inclined to one another with dihedral angles varying between 38.3 (4) and 74.1 (4)°. In the crystal, molecules are linked via O—HCl hydrogen bonds involving one Cl− anion and the water molecule in the equatorial plane, forming an inversion dimer-like arrangement. The water molecule in the axial position is hydrogen-bonded to both Cl− anions. There are also a number of C—HCl hydrogen bonds present, forming a three-dimensional structure. All four alkyl chains are disordered over two positions with refined occupancy ratios of 0.395 (15):0.605 (15), 0.658 (14):0.342 (14), 0.332 (11):0.668 (11) and 0.622 (12):0.378 (12).