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The naphthol-containing mol­ecule of the title compound, C10H6Br2O·CH3OH, crystallized as a methanol monosolvate and is planar to within 0.069 (1) Å for all non-H atoms. In the crystal, mol­ecules are linked by two pairs of O—H...O hydrogen bonds, involving the methanol mol­ecule, forming dimer-like arrangements. The crystal structure is further stabilized by π–π stacking [centroid–centroid distance = 3.676 (2) Å] and Br...Br inter­actions [3.480 (4) and 3.786 (1) Å], forming a three-dimensional structure.
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